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Distillation - an overview | ScienceDirect Topics

is the most commonly used method for the separation of homogeneous liquid mixtures and is based on differences in the boiling points or relative volatility of the constituent components 12 However where the relative volatility is close to unity (eg for the separation of azeotropic mixtures or close boiling components) a third component (ie entrainer solvent or mass separating ) should be added

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